Phosphine-mediated disulfide metathesis in aqueous media.
نویسندگان
چکیده
Dynamic carbohydrate systems have been efficiently generated through phosphine-mediated disulfide metathesis in aqueous media. The protein compatibility and binding features of the dynamic systems were demonstrated in situ using (1)H STD NMR.
منابع مشابه
Phosphine-catalyzed disulfide metathesis.
The reaction between disulfides and phosphines generates a reversible disulfide metathesis process.
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The discovery of highly active catalysts and the success of ionic liquid immobilized systems have accelerated attention to a new class of cationic metathesis catalysts. We herein report the facile syntheses of cationic ruthenium catalysts bearing bulky phosphine ligands. Simple ligand exchange using silver(i) salts of non-coordinating or weakly coordinating anions provided either PPh3 or chelat...
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عنوان ژورنال:
- Chemical communications
دوره 46 44 شماره
صفحات -
تاریخ انتشار 2010